Optimum Biodiesel Production from African Oil Bean Seed Oil Using Antelope Bones and Africa Oil Bean Seed Pod as Catalyst: RSM and ANN as Optimization Tools
DOI:
https://doi.org/10.59573/emsj.7(6).2023.10Ключові слова:
African oil bean seed, Bone, Optimization, Biodiesel, Renewable energyАнотація
Heterogeneous catalyst developed from antelope bones and African oil bean seed pod was used for the production of biodiesel from African oil bean seed oil (AOBSO) characterized by 2.22% free fatty acid (FFA) via transesterification reaction. Characterization showed that the catalyst had high surface area (40.65m2 /g) and large pore diameter (50.85 ?) with CaO being its main constituent. Four independent process variables were optimized using response surface methodology (RSM) and Artificial Neural Network (ANN). The optimization result revealed that a maximum biodiesel yield of 93.25% was achieved using RSM at an optimum condition of temperature (60oC), time (86 minutes), methanol:oil ratio (12:1) and catalyst loading (2 wt.%). Also, using ANN modelling, an optimum yield of 95% was obtained at a temperature, time, methanol:oil ratio and catalyst loading of 57oC, 57 minutes, 7.5:1 and 1 wt.% respectively. The result shows that ANN was better tool at modelling the process because of its higher R2 value and lower RMSE value. Also, the high yield of biodiesel obtained showed that African oil bean seed oil (AOBSO) which is a low-cost feedstock have the potential to be used for biodiesel production.
Посилання
Adekunle, A. S., Oyekunle, J. A. O., Oduwale, A. I., Owootomo, Y., Obisesan, O. R., Elugoke, S. E., Durodola, S. S., Akintunde, S. B., & Oluwafemi, O. S. (2020). Biodiesel potential of used vegetable oils transesterified with biological catalysts. Energy Reports, 6, 2861–2871. https://doi.org/10.1016/j.egyr.2020.10.019
Adepoju, T. F., Ibeh, M. A., & Asuquo, A. J. (2021). Elucidate three novel catalysts synthesized from animal bones for the production of biodiesel from ternary non-edible and edible oil blend: A case of Jatropha curcus, Hevea brasiliensis, and Elaeis guineensis oil. South African Journal of Chemical Engineering, 36(January), 58–73. https://doi.org/10.1016/j.sajce.2021.01.002
Amenaghawon, A. N., Evbarunegbe, N. I., & Obahiagbon, K. (2021). Optimum biodiesel production from waste vegetable oil using functionalized cow horn catalyst: A comparative evaluation of some expert systems. Cleaner Engineering and Technology, 4, 100184. https://doi.org/10.1016/j.clet.2021.100184
Amenaghawon, A. N., Obahiagbon, K., Isesele, V., & Usman, F. (2022). Optimized biodiesel production from waste cooking oil using a functionalized bio-based heterogeneous catalyst. Cleaner Engineering and Technology, 8(April), 100501. https://doi.org/10.1016/j.clet.2022.100501
Aremu, A. K., & Ogunlade, C. A. (2016). Effect of operating parameters on mechanical oil expression from African oil bean seeds. Global Journal of Science Frontier Research: D, Agriculture and Veterinary, 16(1), 19-26.
Ayoola, A. A., Hymore, F. K., Omonhinmin, C. A., Olawole, O. C., Fayomi, O. S. I., Babatunde, D., & Fagbiele, O. (2019). Analysis of waste groundnut oil biodiesel production using response surface methodology and artificial neural network. Chemical Data Collections, 22, 100238. https://doi.org/10.1016/j.cdc.2019.100238
Balajii, M., & Niju, S. (2020). Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil. Renewable Energy, 146, 2255–2269. https://doi.org/10.1016/j.renene.2019.08.062
Betiku, E., Okeleye, A. A., Ishola, N. B., Osunleke, A. S., & Ojumu, T. V. (2019). Development of a Novel Mesoporous Biocatalyst Derived from Kola Nut Pod Husk for Conversion of Kariya Seed Oil to Methyl Esters: A Case of Synthesis, Modeling and Optimization Studies. Catalysis Letters, 149(7), 1772–1787. https://doi.org/10.1007/s10562-019-02788-6
Costarrosa, L., Leiva-Candia, D. E., Cubero-Atienza, A. J., Ruiz, J. J., & Dorado, M. P. (2018). Optimization of the transesterification of waste cooking oil with mg-al hydrotalcite using response surface methodology. Energies, 11(2), 302. https://doi.org/10.3390/en11020302
Dharma, S., Masjuki, H. H., Ong, H. C., Sebayang, A. H., Silitonga, A. S., Kusumo, F., & Mahlia, T. M. I. (2016). Optimization of biodiesel production process for mixed Jatropha curcas-Ceiba pentandra biodiesel using response surface methodology. Energy Conversion and Management, 115, 178–190. https://doi.org/10.1016/j.enconman.2016.02.034
Madai, I. J., Chande Jande, Y. A., & Kivevele, T. (2020). Fast rate production of biodiesel from neem seed oil using a catalyst made from banana peel ash loaded with metal oxide (Li-CaO/Fe2(SO4)3). Advances in Materials Science and Engineering, 2020. https://doi.org/10.1155/2020/7825024
Mahmood, H., Iqbal, T., Haider, C., & Javaid, A. (2020). Sustainable biodiesel production from waste cooking oil utilizing waste ostrich (Struthio camelus) bones derived heterogeneous catalyst. Fuel, 277(April), 118091. https://doi.org/10.1016/j.fuel.2020.118091
Marinković, M., Waisi, H., Blagojević, S., Zarubica, A., Ljupković, R., Krstić, A., & Janković, B. (2022). The effect of process parameters and catalyst support preparation methods on the catalytic efficiency in transesterification of sunflower oil over heterogeneous KI/Al2O3-based catalysts for biodiesel production. Fuel, 315(November 2021). https://doi.org/10.1016/j.fuel.2022.123246
Nasrollahzadeh, M., Soheili Bidgoli, N. S., Shafiei, N., Soleimani, F., Nezafat, Z., & Luque, R. (2020). Low-cost and sustainable (nano)catalysts derived from bone waste: catalytic applications and biofuels production. Biofuels, Bioproducts and Biorefining, 14(6), 1197–1227. https://doi.org/10.1002/bbb.2138
Ndukwu, M. C., & Onyeoziri, C. I. (2022). African oil bean seed as feedstock for bio-oil and biodiesel production and on the effects of thermal pre-treatments on the quality of the bio-oil. Biomass Conversion and Biorefinery, 12(7), 2799–2810. https://doi.org/10.1007/s13399-020-00754-6
Obadiah, A., Ajji, G., Vasanth, S., & Raman, K. (2012). Bioresource Technology Biodiesel production from Palm oil using calcined waste animal bone as catalyst. Bioresource Technology, 116, 512–516. https://doi.org/10.1016/j.biortech.2012.03.112
Obahiagbon, K., & Ahonkhai, D. O. (2023). Optimized Biodiesel Production from Waste Cooking Oil Using Nickel (II) Nitrate Doped Chicken Manure as Catalyst. European Journal of Applied Sciences, 11(3), 812–824. https://doi.org/10.14738/aivp.113.14891
Odetoye, T. & Amusan, G. (2019). Cocoa pod ash as biodiesel catalyst for biodiesel production from waste chicken fat. CIGR Journal, 21(4), 141–151.
Ogunsola, A. D., Durowoju, M. O., Alade, A. O., Jekayinfa, S. O., & Ogunkunle, O. (2022). Modeling and optimization of two-step shea butter oil biodiesel synthesis using snail shells as heterogeneous base catalysts. Energy Advances, 2, 113–128. https://doi.org/10.1039/d1ya00042j
Okonkwo, C. P., Ajiwe, V. I. E., Ikeuba, A. I., Emori, W., Okwu, M. O., & Ayogu, J. I. (2023).Production and performance evaluation of biodiesel from Elaeis guineensis using natural snail shell-based heterogeneous catalyst: kinetics, modeling and optimisation by artificial neural network . RSC Advances, 13(28), 19495–19507. https://doi.org/10.1039/d3ra02456c
Yusuff, A. S., & Adesina, O. A. (2020). Biodiesel synthesis from palm olein oil using anthill as catalyst. Journal of Chemical Technology and Metallurgy, 55(2), 300–306.
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